She made a glamorous appearance at the British Fashion Awards when she stormed the red carpet in a vintage Valentino couture gown.

And Anne Hathaway pulled off yet another stunning look as she made a quick change for the afterparty on Cadogan Square in London on Monday night.

The Devil Wears Prada star, 41, exuded glamour in her new ensemble as she partied the night away with the likes of FKA twigs, Gwyneth Paltrow and Rosie Huntington-Whiteley.

She put her sensational figure on display as she slipped into a strapless scarlet mini dress with a ruffled skirt that resembled a rose.

She added to the glamour by donning thigh high leather boots and accessorising with a glittering diamond necklace.

Anne Hathaway transformed into an English rose in a petal-inspired mini dress as she joined FKA twigs at the British Fashion Awards afterparty on Cadogan Square in London on Monday

Also making a nod to flower power was twigs, who commanded attention in a racy black mini dress with a petal print along the bodice.

The songstress, 35, whose real name is Tahliah Debrett Barnett, sent temperatures soaring as she went braless under the cut out backless floral number.

Showing off her endless pins, she elevated her frame in a pair of towering dazzling silver heels and toted her belongings in a coordinated clutch bag.

She looked more loved-up than ever during the rare appearance with her boyfriend Jordan Hemingway as they were spotted walking hand-in-hand out of the post-awards bash.

Also attending the party with their partner was Gwyneth, 51, who strutted out with husband Brad Falchuk, 52.

The actress looked gorgeous in a strapless red Valentino dress with plunging cut-out neckline that tease a glimpse of her ample cleavage.

Gwyneth also wore a matching sheer coat which was adorned with perfectly placed sequins and feathers.

The Shakespeare in Love star accessorised with beaded bracelets and earrings, forging a necklace and letting the ultra chic outfit speak for itself.

Anne Hathaway exuded glamour in her new ensemble as she pulled off yet another stunning look on the night celebrating fashion

Earlier in the night, she made a glamorous appearance at the British Fashion Awards when she stormed the red carpet in a vintage Valentino couture gown

She put her sensational figure on display as she slipped into a strapless scarlet mini dress with a ruffled skirt that resembled a rose

She added to the glamour by donning thigh high leather boots and accessorising with a glittering diamond necklace

Flying solo on the night was Rosie, 36, who was not joined by fiancé Jason Statham, 56, for the soiree.

The model, 36, flaunted her toned and trimmed abs in a gorgeous Grecian gown which boasted cut outs as well as a long elegant train.

Rosie’s showstopping dress also featured a flowing skirt with sheer panels, teasing a glimpse of her long toned legs.

She swept back her blonde locks and accentuated her dainty features with a glamorous make-up palette and classic red lip.

The stunner accessorised with diamond earrings and a chunky silver cuff while toting her essentials in clutch.

A-listers such as Kate Moss, Amal Clooney and Gwyneth Paltrow walked the red carpet at the British Fashion Awards 2023.

The event, presented by jewellery brand Pandora returned to the iconic London venue, the Royal Albert Hall on Monday evening.

The evening, hosted by British broadcaster Maya Jama and musical artist Kojey Radical, celebrated 16 awards. TFA nominees and winners are voted for by an international judging panel made up of over 1000 industry experts.

The event serves as the main fundraiser for the BFC Foundation. which supports the future growth and success of the British fashion industry through its focus on education, grant-giving, and business mentoring.

The BFC also went back to having some gender-based design awards for the first time since the pandemic, splitting the best British designers into menswear and womenswear categories.

Leading industry figures were recognised such as Valentino Garavani with the Outstanding Achievement award, make-up artist Charlotte Tilbury with the Special Recognition Award, and the late Joe Casely-Hayford with a posthumous special recognition award.

Sam Smith accepted the Cultural Innovator trophy as they were honoured for creating viral fashion moments, such as their unforgettable latex clad appearance at the 2023 Brit Awards.

Speaking about Sam’s award Caroline Rush, chief executive officer at the British Fashion Council, said Sam was is ‘a true cultural innovator who has fearlessly pushed the boundaries of both fashion and entertainment.

‘Smith’s unapologetic and groundbreaking style choices have dominated the industry in 2023 and we are incredibly grateful for their continued support of U.K. designers.’

Daphne Guinness was also in attendance at the party but made a dramatic fall as she teetered out of the bash in her towering heels 

The awards ceremony kicked off in style, with global superstar Usher welcoming the audience of leading designers, artists, creatives, and tastemakers for a night celebrating the global fashion community, asking ‘How does fashion make you feel?’.

The evening started with METTE’s Pandora performance, followed with a performance from Cultural Innovator Award winner Sam Smith and ended with a DJ set by Skepta at the afterparty.

The British fashion industry paid tribute to Dame Vivienne Westwood and her fearless approach to design and activism and recognised Joe Casely-Hayford with a posthumous Special Recognition Award for his incredible contributions to fashion and culture.